1345628-08-1

Basic information

• Product Name: (11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide
• Synonyms: (11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide;(11aR)- 5-oxide-3,7-di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin;(11aR)-3,7-Di-9-anthracenyl-10,11,12,13-tetrahydro-5- hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2] dioxaphosphocin;(11aR)-3,7-Di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,99%e.e.;(11aR)-3,7-Di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 98%, (99% ee)
• CAS NO: 1345628-08-1
• Molecular Formula: C45H32O4P
• Molecular Weight: 667.706941
• Mol File: 1345628-08-1.mol

Chemical Properties

• Appearance: /
• Density: 1.46
• PKA: 1.14±0.20(Predicted)
• CAS DataBase Reference: (11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide(1345628-08-1)
• EPA Substance Registry System: (11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide(1345628-08-1)

Safety Data

• Hazardous Substances Data: 1345628-08-1(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Applications:
(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide is used as a potential drug candidate due to its unique chemical structure and properties. It may have therapeutic effects in various medical conditions, although further research is needed to explore its full potential.
Used in Organic Chemistry Research:
(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide is used as a building block for the synthesis of other complex organic compounds. Its unique structure makes it an interesting subject for further research and exploration in the field of organic chemistry, potentially leading to the development of new compounds with various applications.
Used in Chemical Industry:
(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-anthracenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide may also find use in the chemical industry for various purposes, such as in the development of new materials, catalysts, or other chemical processes. Its specific properties and structure could contribute to innovative solutions in this field.

Upstream product

• 100622-34-2 anthracene-9-boronic acid 
• 1345628-15-0 (R)-6,6'-bis(9-anthracenyl)-1,1'-spirobiindane-7,7'-diol 
• 1258276-29-7 C₂₁H₂₂I₂O₄ 
• 1345628-13-8 (R)-6,6'-diiodo-7,7'-bis(methoxymethoxy)-2,2',3,3'-tetrahydro-1,1'-spirobiindane 

Relevant articles and documents

The catalytic asymmetric Fischer indolization

The first catalytic asymmetric Fischer indolization is reported. In the presence of a 5 mol % loading of a novel spirocyclic chiral phosphoric acid, 4-substituted cyclohexanone-derived phenylhydrazones undergo a highly enantioselective indolization. Efficient catalyst turnover was achieved by the addition of a weakly acidic cation exchange resin, which removes the generated ammonia. The reaction can be conducted under mild conditions and gives various 3-substituted tetrahydrocarbazoles in generally high yields.