1345735-76-3Relevant academic research and scientific papers
Ferrocenyl-substituted (μ5-hydroxyalkylcyclohexadienyl) tricarbonylmanganese complexes: Synthesis, structural determinations, and formation of carbenium ions
Eloi, Antoine,Poizat, Mael,Hautecoeur, Albin,Panossian, Armen,Rose-Munch, Francoise,Rose, Eric
, p. 5564 - 5567 (2012/01/04)
Ferrocenyl-substituted (μ5-hydroxyalkylcyclohexadienyl) -tricarbonylmanganese complexes have been synthesized as well as the corresponding carbenium dinuclear complexes after dehydroxylation. Studies in solution and in the solid state of these zwitterionic species show not only the electronic influence of the positive charge on the μ5-Mn complex but also the participation of the two metal atoms in the stabilization of this charge. Catalytic tests show a high activity of these cations as Lewis acids in a typical Diels-Alder reaction.
