134576-02-6

Basic information

• Product Name: (Z)-4-Methylsulfanyl-1,2,5-triphenyl-pent-3-en-2-ol
• Synonyms: (Z)-4-Methylsulfanyl-1,2,5-triphenyl-pent-3-en-2-ol
• CAS NO: 134576-02-6
• Molecular Weight: 360.52
• Mol File: 134576-02-6.mol

Chemical Properties

• CAS DataBase Reference: (Z)-4-Methylsulfanyl-1,2,5-triphenyl-pent-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4-Methylsulfanyl-1,2,5-triphenyl-pent-3-en-2-ol(134576-02-6)
• EPA Substance Registry System: (Z)-4-Methylsulfanyl-1,2,5-triphenyl-pent-3-en-2-ol(134576-02-6)

Safety Data

• Hazardous Substances Data: 134576-02-6(Hazardous Substances Data)

Upstream product

• 13636-88-9 3,3-bis(methylthio)-1-phenylprop-2-en-1-one 
• 6921-34-2 benzylmagnesium chloride 

Downstream Products

• 104750-16-5 1-Benzyl-3-phenylnaphthalene 

Relevant articles and documents

CYCLOAROMATIZATION OF α-OXOKETENDITHIOACETALS WITH BENZYLMAGNESIUM CHLORIDE: A NOVEL NAPHTHALENE ANNELATION REACTION

α-Oxoketendithioacetals derived from acyclic and cyclic ketones are shown to react with benzylmagnesium chloride to give novel naphthoannelated aromatic compounds by sequential 1,4- and 1,2-additions followed by subsequent cycloaromatization of the resulting carbinols.

Cycloaromatization of α-oxoketene dithioacetals and β-oxodithioacetals with benzyl-,1-(naphthylmethyl) and 2-(naphthylmethyl)magnesium halides: Synthesis of condensed polynuclear aromatic hydrocarbons

An efficient route for the synthesis of substituted naphthalenes, phenanthrenes and other polynuclear aromatic hydrocarbons has been developed. The methodology involves 1,2- (or sequential 1,4- and 1,2-) addition of either benzyl, 1-(naphthylmethyl) or 2-(naphthylmethyl) magnesium halides to α-oxoketene dithioacetals or β-oxodithioacetals followed by borontrifluoride etherate catalyzed cycloaromatization of the resulting carbinols.