134577-26-7Relevant academic research and scientific papers
A new synthetic route for the preparation of β-acyloxy mercaptans via the addition of thioacids to epoxides
Abbasi, Mohammad
experimental part, p. 2608 - 2610 (2012/07/02)
A new synthetic route for the preparation of S-benzylated β-acyloxy mercaptans starting from the one-pot reaction of thioacids and epoxides using a silica gel/Et3N combined catalyst is described. The thiol functionality in the crude product is then protected via benzylation and the corresponding thioethers are isolated after chromatography.
New Addition Reactions of Cyclic Ethers with Esters and Thioesters Catalyzed by Quaternary Ammonium Salts or Crown Ether Complexes
Nishikubo, Tadatomi,Sato, Kazuya
, p. 697 - 700 (2007/10/02)
A new addition reaction of 3-benzyloxymethyl-3-methyloxetane with S-phenyl thioacetate proceeded to give 3-benzyloxy-2-methyl-2-phenylthiomethylpropyl acetate catalyzed by 18-crown-6-potassium phenoxide complex.N-(2-Acetoxyethyl)-N-(2-phenoxyethyl)acetamide was also synthesized in high yield by the addition reaction of 5-methyl-4,6-dioxa-1-azabicyclo octane with phenyl acetate, using tetrabutylammonium salts as catalysts.
