1346008-78-3

Basic information

• Product Name: (E)-4-[5-(2-methyl-3-oxopropenyl)-furan-2-yl]benzaldehyde
• Synonyms: (E)-4-[5-(2-methyl-3-oxopropenyl)-furan-2-yl]benzaldehyde
• CAS NO: 1346008-78-3
• Molecular Weight: 240.258
• Mol File: 1346008-78-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-4-[5-(2-methyl-3-oxopropenyl)-furan-2-yl]benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-[5-(2-methyl-3-oxopropenyl)-furan-2-yl]benzaldehyde(1346008-78-3)
• EPA Substance Registry System: (E)-4-[5-(2-methyl-3-oxopropenyl)-furan-2-yl]benzaldehyde(1346008-78-3)

Safety Data

• Hazardous Substances Data: 1346008-78-3(Hazardous Substances Data)

Upstream product

• 874-66-8 (E)-3-(furan-2-yl)-2-methylacrylaldehyde 
• 1122-91-4 4-bromo-benzaldehyde 

Relevant articles and documents

Phosphine-free palladium catalytic system for the selective direct arylation of furans or thiophenes bearing alkenes and inhibition of heck-type reaction

Palladium acetate associated to potassium carbonate as catalytic system has been found to efficiently catalyse the direct 5-arylation of furans or thiophenes bearing enal, enone or acrylate functions at carbon C-2, and to inhibit the Heck-type reaction. The nature of the base is crucial to control the selectivity of the arylation. In the presence of electron-deficient aryl bromides and potassium carbonate as the base, the direct arylation is favoured, whereas the use of potassium fluoride gave selectively the Heck-type product, and tri-n-butylamine the reductive addition product. Copyright