1346129-90-5

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 150-76-5 4-methoxy-phenol 
• 20443-88-3 2-(4-methoxyphenoxy)tetrahydro-2H-pyran 
• 74-88-4 methyl iodide 

Downstream Products

• 1346129-91-6 2-iodo-4-methoxy-6-methylphenol 
• 1346129-92-7 1,3-bis(2-iodo-4-methoxy-6-methylphenoxy)propane 
• 1449252-28-1 C₂₀H₂₄N₂O₄ 
• 886503-93-1 5-methoxy-3-methylsalicylaldehyde 

Relevant academic research and scientific papers

Cobalt-salen complex-catalyzed oxidative generation of alkyl radicals from aldehydes for the preparation of hydroperoxides

Catalytic generation of alkyl radicals from aldehydes via oxidative deformylation was realized using a cobalt-salen complex with H2O 2. The deformylation was thought to proceed through homolytic cleavage of peroxohemiacetal intermediates to provide even primary alkyl radicals under mild conditions. Variously substituted and functionalized hydroperoxides were obtained from corresponding aldehydes in good yield.

PROCESS FOR SELECTIVELY POLYMERIZING ETHYLENE AND CATALYST THEREFOR

The present invention generally relates to a process that selectively polymerizes ethylene in the presence of an alpha-olefin, and to a metal-ligand complex (precatalyst) and catalyst useful in such processes, and to related compositions. The present invention also generally relates to ligands and intermediates useful for preparing the metal-ligand complex and to processes of their preparation.