1346164-42-8Relevant articles and documents
Synthesis of sulfur-substituted α-stereogenic amides and ketones: Highly enantioselective sulfa-michael additions of 1,4-dicarbonylbut-2-enes
Zhao, Fangli,Zhang, Wen,Yang, Yuanyong,Pan, Yuanhang,Chen, Wenchao,Liu, Hongjun,Yan, Lin,Tan, Choon-Hong,Jiang, Zhiyong
supporting information; experimental part, p. 2624 - 2630 (2011/12/01)
Conjugate addition to 1,4-dicarbonylbut-2-enes will generate an α-stereogenic center with respect to one of the carbonyl groups, which informally, can be considered as an inversion of normal reactivity patterns or umpolung protocol. In this paper, the add