134617-20-2Relevant academic research and scientific papers
Intramolecular 1,3-Dipolar Cycloadditions of Thiocarbonyl S-Sulfides (Thiosulfines) with Non-activated Alkenes
Saito, Takao,Shundo, Yoshimune,Kitazawa, Satoshi,Motoki, Shinichi
, p. 600 - 602 (2007/10/02)
Novel examples are described that involve unequivocal evidence for the existence of thiocarbonyl S-sulfides via intramolecular -trapping by non-activated alkenes.
INTRAMOLECULAR ENE REACTION ON UNSATURATED THIOKETONES
Motoki, Shinichi,Watanabe, Tsumoru,Saito, Takao
, p. 189 - 192 (2007/10/02)
The thermal cyclization of o-(2-substituted allyloxy)thiobenzophenones giving 1,5-oxathiocine derivatives is reported.This is the first example of the new type intramolecular ene reaction of unsaturated thioketones.
