134619-71-9Relevant academic research and scientific papers
Boron trihalide mediated haloallylation of aryl aldehydes and its application to the preparation of (E)-1,3-dienes
Quinn, Michael P.,Yao, Min-Liang,Yong, Li,Kabalka, George W.
experimental part, p. 3815 - 3820 (2012/01/05)
In the presence of boron trihalides, aryl aldehydes couple readily with allylmetals to afford haloallylated products. The reactions tolerate a variety of functional groups. Simple aqueous workup of haloallylation reactions, followed by treatment with 1,8-
Boron trihalide mediated haloallylation of aryl aldehydes: Reaction and mechanistic insight
Yao, Min-Liang,Borella, Scott,Quick, Travis,Kabalka, George Walter
, p. 776 - 778 (2008/09/20)
The reaction of aryl aldehydes with allylsilanes in the presence of boron trihalides produces haloallylated products. Mechanistic details are presented. The Royal Society of Chemistry.
Halogenative Allylation and Reduction of Aromatic Acetals by Double Substitution of Alkoxyl Groups in Acetal
Oriyama, Takeshi,Iwanami, Katsuyuki,Tsukamoto, Kazuhisa,Ichimura, Yuichi,Koga, Gen
, p. 1410 - 1412 (2007/10/02)
In the presence of excessive amount of acetyl halide along with a catalytic amount of tin(II) halide, aromatic acetals react with allyltrimethylsilane or triethylsilane to give α-allylbenzyl halides or benzyl halides, respectively, in good to excellent yields.
