1346255-05-7Relevant articles and documents
Hydroalumination of silylacetylenes: A novel and highly stereoselective synthesis of (E)-telluro(silyl)ketene acetals and their applications in Sonogashira cross-coupling reactions
Kawasoko, Cristiane Y.,Nazario, Carlos E.D.,Santana, Amanda S.,Viana, Luiz H.,Hurtado, Gabriela R.,Marques, Francisco A.,Frensch, Gustavo,De Oliveira, Paulo R.,Guerrero Jr., Palimécio G.,Carvalho, Diego B.,Baroni, Adriano C.M.
experimental part, p. 6067 - 6071 (2011/11/29)
The hydroalumination of silylacetylenes with DIBAL-H followed by the addition of n-butyllithium generated in situ the (Z)-β-vinylorganosilane alanates intermediates, which were trapped with butyltellurenyl bromide (C 4H9TeBr), furnis