1346258-52-3

Upstream product

• 654077-23-3 (2R)-1,2-(cyclohexylidenedioxy)tridecan-3-one 
• 1346258-50-1 C₃₆H₅₂O₅SSi 
• 1346258-51-2 (2R,3R)-1,2-epoxy-3-O-tert-butyldiphenylsilyl-tridecan-3-ol 
• 626-88-0 1-bromo-5-methylpentane 
• 1346258-49-8 (2R,3R)-3-O-tert-butyldiphenylsilyl-tridecane-1,2,3-triol 
• 1346258-46-5 (2R,3R)-1,2-O-cyclohexylidene-3-O-tert-butyldiphenylsilyltridecane-1,2,3-triol 

Downstream Products

• 1346258-53-4 C₄₂H₆₄O₄SSi 

Relevant academic research and scientific papers

An enantiodivergent synthesis of both (+)- and (-)-disparlure from (R)-2,3-cyclohexylideneglyceraldehyde

Reduction of ketone 3 derived from (R)-2,3-cyclohexylideneglyceraldehyde 1 with some common hydrides took place with syn-selectivity. The resulting major product 4a has been exploited as a common chiral template to prepare both enantiomers Ia,b of disparlure.