134641-27-3Relevant academic research and scientific papers
Exploring bis(cyclometalated) ruthenium(II) complexes as active catalyst precursors: Room-temperature alkene-alkyne coupling for 1,3-diene synthesis
Zhang, Jing,Ugrinov, Angel,Zhang, Yong,Zhao, Pinjing
supporting information, p. 8437 - 8440 (2014/08/18)
Described is the development of a new class of bis(cyclometalated) ruthenium(II) catalyst precursors for C-C coupling reactions between alkene and alkyne substrates. The complex [(cod)Ru(3-methallyl)2] reacts with benzophenone imine or benzophe
Ruthenium Complex-catalysed Highly Selective Codimerisation of Acetylenes and Alkenes
Mitsudo, Take-aki,Zhang, Shi-Wei,Nagao, Masaki,Watanabe, Yoshihisa
, p. 598 - 599 (2007/10/02)
2,4-Dienes are prepared in high yields with high regioselectivity by the codimerisation of acetylenes and alkenes in the presence of a catalytic amount of Ru(cod)(cot) at 80 deg C; cod = cycloocta-1,5-diene, cot = cycloocta-1,3,5-triene.
