134641-68-2Relevant academic research and scientific papers
Reaction of 2-nitro and 3-nitro-2-cyclohexenone acetals: Preparation of useful intermediates
Vankar,Bawa,Kumaravel
, p. 2027 - 2040 (1991)
Preparation of 2-nitro-2-cyclohexenone acetal 31 starting from 2-nitrocyclohexanone acetal 29 has been reported for the first time. This compound as well as 3-nitro-2-cyclohexenone acetal 1, whose synthesis has been reported by us earlier, react with a variety of nucleophiles to form highly functionalised intermediates. One of them viz. 21 is converted into a bicyclic α-methylene-γ-lactone 24 using radical chemistry.
