134644-17-0Relevant academic research and scientific papers
Bimetallic Nanoshells as Platforms for Metallo- and Biometallo-Catalytic Applications
Kisukuri, Camila M.,Palmeira, Dayvson J.,Rodrigues, Thenner S.,Camargo, Pedro H.C.,Andrade, Leandro H.
, p. 171 - 179 (2016/01/25)
The use of gold, silver, platinum and palladium for preparation of bimetallic nanoshells (AgAu, AgPt, and AgPdNSs, respectively) and their use for metallo- and bio-metallo catalytic applications have been described. Bimetallic nanoshells (metallo-catalysts) were employed for silane oxidation to silanols and hydrogen (H2) production. Fast and efficient oxidation of several silanes was observed after only 1 h at room temperature, by employing AgPd NSs as catalyst, acetone as solvent, and water as oxidant. Interestingly, bio-metallo-catalysts (NSs-CALB) prepared from lipase attachment to the bimetallic nanoshells, displayed promising bi-catalytic activities (enzymatic: transesterification; metallic: silane oxidation).
Rates and Mechanism for the Solvolyses of 2,2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzyl p-Toluenesulfonates. α-Silicon Effect on the Stability of Benzylic Cations in Solution
Shimizu, Nobujiro,Osajima, Erika,Tsuno, Yuho
, p. 1145 - 1152 (2007/10/02)
α-Silicon effect on the benzylic solvolysis has been investigated.The solvolysis of 2,2-dimethyl-2-sila-1-indanyl bromide in aq acetone exhibits a linear response to the solvent ionizing power YBr, with a slope m close to unity (m = 0.93) and g
