1346459-40-2Relevant academic research and scientific papers
New preparation of benzylic aluminum and zinc organometallics by direct insertion of aluminum powder
Bluemke, Tobias D.,Groll, Klaus,Karaghiosoff, Konstantin,Knochel, Paul
supporting information; experimental part, p. 6440 - 6443 (2012/01/15)
The reaction of commercial Al-powder (3 equiv) and InCl3 (1-5 mol %) with benzylic chlorides provides various functionalized benzylic aluminum sesquichlorides under mild conditions (THF, 20 °C, 3-24 h) without homocoupling (5%). These new benz
