134651-20-0

Upstream product

• 134680-58-3 (3aR,4R,5S,6R,7S)-5,6,7-Tris-benzyloxy-3,3a,4,5,6,7-hexahydro-benzo[c]isoxazol-4-ol 
• 134680-57-2 (1S,2R,3S,4R,5S)-3,4,5-tribenzyloxy-2-hydroxy-8-oxa-7-azabicyclo<4.3.0>non-6-ene 
• 136892-47-2 (2R,3S,4S,5R,6R)-2,3,4-Tris-benzyloxy-5-hydroxy-6-hydroxymethyl-cyclohexanone 
• 134680-59-4 (2R,3S,4S,5R,6S)-2,3,4-tribenzyloxy-5-hydroxy-6-hydroxymethylcyclohexanone 
• 128184-65-6 2,3,4-tri-O-benzyl-6,7-dideoxy-D-galacto-hept-6-enose-oxime 
• 134680-55-0 methyl 2,3,4-tri-O-benzyl-α-D-galacto-hexodialdo-1,5-pyranoside 
• 134651-18-6 methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galacto-hept-6-enopyranoside 
• 139285-94-2 1D-4,5,6-tri-O-benzyl-2-deoxy-2-<<(1-methylethyl)diethylsilyl>oxy>methyl-chiro-inositol 
• 134651-19-7 1D-4,5,6-tri-O-benzyl-2-deoxy-2-hydroxymethyl-chiro-inositol 
• 139285-93-1 (2R,3S,4S,5R)-2,3,4-Tris-benzyloxy-5-hydroxy-hept-6-enal 
• 4356-80-3 methyl 2,3,4-tri-O-benzyl-α-D-galactopyranoside 
• 128184-69-0 Methanesulfonic acid (1R,2R,3R,4R,5R,6R)-2,3,4-tris-benzyloxy-5-(diethyl-isopropyl-silanyloxy)-6-(diethyl-isopropyl-silanyloxymethyl)-cyclohexyl ester 

Relevant academic research and scientific papers

A Divergent Route for a Total Synthesis of Cyclophellitol and Epicyclophellitol from a Oxabicyclic Glycoside Prepared from D-Glucal

D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.

Total syntheses of glucosidase inhibitors, cyclophellitols

A β-D-glucosidase inhibitor, cyclophellitol heptane-2,3,4-triol, 1> and its epoxide diastereomer, 1,6-epicyclophellitol (2) have been synthesized by using an intramolecular -cycloaddition of a n