1346696-94-3

Basic information

• Product Name: (1-(3-phenylprop-2-ynyl)cyclohex-2-enylsulfonyl)benzene
• Synonyms: (1-(3-phenylprop-2-ynyl)cyclohex-2-enylsulfonyl)benzene
• CAS NO: 1346696-94-3
• Molecular Weight: 336.455
• Mol File: 1346696-94-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1-(3-phenylprop-2-ynyl)cyclohex-2-enylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1-(3-phenylprop-2-ynyl)cyclohex-2-enylsulfonyl)benzene(1346696-94-3)
• EPA Substance Registry System: (1-(3-phenylprop-2-ynyl)cyclohex-2-enylsulfonyl)benzene(1346696-94-3)

Safety Data

• Hazardous Substances Data: 1346696-94-3(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 1346696-90-9 (1-(prop-2-ynyl)cyclohex-2-enylsulfonyl)benzene 
• 873-55-2 sodium benzenesulfonate 
• 87413-32-9 (cyclohex-2-enylsulfonyl)benzene 
• 1521-51-3 rac-3-bromocyclohexene 

Relevant articles and documents

Nature of the intermediates in gold(I)-catalyzed cyclizations of 1,5-enynes

The carbene or carbocationic nature of the intermediates in the gold-catalyzed cycloisomerization of 1,5-enynes can be revealed, depending on the ligands on the gold catalysts. Gold complexes with highly electron-donating ligands promote reactions that proceed via intermediates with carbene-like character, leading to products with a bicyclo[3.1.0]hexene skeleton. The intermediate cyclopropyl endo-gold carbenes formed in this cyclization have been trapped, for the first time, to give biscyclopropane derivatives in a reaction that proceeds in a concerted fashion, according to DFT calculations.