134692-09-4Relevant academic research and scientific papers
Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes
Jeganmohan, Masilamani,Shanmugasundaram, Muthian,Chang, Kuo-Jui,Cheng, Chien-Hong
, p. 2552 - 2553 (2007/10/03)
The addition reaction of silylstannanes with allenes in the presence of Pd2(dba)3·dba in toluene affords (E)-alkenylsilanes having an allylstannane moiety exclusively in good to excellent yields.
Palladium-catalysed addition of tin-tin and tin-silicon bonds to allenes
Mitchell, Terence N.,Schneider, Ulrich
, p. 319 - 327 (2007/10/02)
Hexamethyl-, hexaethyl- and hexabutyl-ditin add to a variety of allenes in the presence of Pd(PPh3)4; the reaction is reversible.Trimethylsilyltrimethyl- and -tributyl-stannane also add under comparable conditions, the silyl moiety becoming attached to the central carbon atom of the allene skeleton; this reaction is, however, apparently not reversible.
