134733-21-4

Basic information

• Product Name: (R)-(-)-10-Phenyl-10,11,12-triaza-Δ¹¹-bicyclo<7.3.0>dodec-1-ene
• CAS NO: 134733-21-4
• Molecular Weight: 241.336
• Mol File: 134733-21-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-(-)-10-Phenyl-10,11,12-triaza-Δ¹¹-bicyclo<7.3.0>dodec-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-10-Phenyl-10,11,12-triaza-Δ¹¹-bicyclo<7.3.0>dodec-1-ene(134733-21-4)
• EPA Substance Registry System: (R)-(-)-10-Phenyl-10,11,12-triaza-Δ¹¹-bicyclo<7.3.0>dodec-1-ene(134733-21-4)

Safety Data

• Hazardous Substances Data: 134733-21-4(Hazardous Substances Data)

Upstream product

• 1123-11-1 (S)-(-)-1,2-Cyclononadiene 
• 622-37-7 Phenyl azide 

Relevant articles and documents

Aryl Azide-Allene Cycloaddition. The Contrasting Behavior of Two Simple Allenes, 1,2-Cyclononadiene and 1,2-Propadiene

1,2-Cyclononadiene (1) reacts with phenyl azide (2a) and 4-bromophenyl azide (2b) to give conjugated triazoline adducts 3a and 3b, respectively. (R)-(+)-1 and 2a react to give (S)-(+)-3a, which is consistent with a concerted cycloaddition mechanism.The reaction of 1,2-propadiene (6) and 2a gives triazoles 8 and 10 plus compound 18 in nearly equal amounts.The formation of these products is rationalized by a scheme involving initial formation of triazolines 7 and 9.Triazoline 3a is slowly isomerized by sodium ethoxide or N,N-dimethylaniline to triazole 20.