134750-16-6

Basic information

• Product Name: (5Z)-5,6-bis(carbomethoxy)-5,8-decadien-2-one
• CAS NO: 134750-16-6
• Molecular Weight: 268.31
• Mol File: 134750-16-6.mol

Chemical Properties

• CAS DataBase Reference: (5Z)-5,6-bis(carbomethoxy)-5,8-decadien-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (5Z)-5,6-bis(carbomethoxy)-5,8-decadien-2-one(134750-16-6)
• EPA Substance Registry System: (5Z)-5,6-bis(carbomethoxy)-5,8-decadien-2-one(134750-16-6)

Safety Data

• Hazardous Substances Data: 134750-16-6(Hazardous Substances Data)

Upstream product

• 598-32-3 2-hydroxy-3-butene 
• 762-42-5 dimethyl acetylenedicarboxylate 

Relevant articles and documents

Diazadiene-stabilized palladacyclopent-2-enes and the catalytic addition of various allylic systems to dimethyl acetylenedicarboxylate

With diazadiene (dad = RN=CR'-CR'=NR) as co-ligand the palladacyclopent-2-enes 3 formed by direct coupling of a 1-alkene and an acetylenedicarboxylic acid ester can be trapped.With activated 1-alkenes such as allylic alcohols the reaction becomes catalytic, yielding linear addition-products 4-11 from two molecules of the alkene and one molecule of the alkyne; no simple reductive elimination occurs, but instead elimination of one mole of water takes place.Allylic esters react analogously but a cyclic 1:2-addition-product 15 (also formed by loss of the leaving group) is the main product.The elimination of the leaving group is probably the driving force of the reaction, since only β-H-transfer that make elimination possible are observed.