134750-75-7Relevant academic research and scientific papers
Preparation and Enantiomer Recognition Behaviour of Crown Ethers containing cis-1-Phenylcyclohexane-1,2-diol and trans-1,2-Diphenylcyclohexane-1,2-diol as a Chiral Subunit
Naemura, Koichiro,Miyabe, Hajime,Shingai, Yasuhiro,Tobe, Yoshito
, p. 1073 - 1078 (2007/10/02)
Pig liver esterase-mediated hydrolysis of (+/-)-cis-2-acetoxy-1-phenylcyclohexanol 5 gave (+)-cis-1-phenylcyclohexane-1,2-diol 4 of high optical purity, from which (-)-trans-1,2-diphenylcyclohexane-1,2-diol 8 has been prepared.Using these diols (+)-4 and
Synthesis and Enantiomer Recognition of Crown Ethers containing Cyclohexane-1,2-diol Derivatives as the Chiral Centre and Enzymatic Resolution of the Chiral Subunits
Naemura, Koichiro,Miyabe, Hajime,Shingai, Yasuhiro
, p. 957 - 959 (2007/10/02)
The cyclohexane-1,2-diol derivatives 1 and 4 of high optical purity have been prepared by enantioselective hydrolysis of their acetates (+/-)-2 and (+/-)-5 using pig liver esterase.The enantiomer recognition behaviour of the chiral crown ethers 11, 14, 15
