134765-49-4

Basic information

• Product Name: (6S,7R)-6-Hydroxy-7-trimethylsilanyl-non-8-enoic acid methyl ester
• CAS NO: 134765-49-4
• Molecular Weight: 258.433
• Mol File: 134765-49-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (6S,7R)-6-Hydroxy-7-trimethylsilanyl-non-8-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (6S,7R)-6-Hydroxy-7-trimethylsilanyl-non-8-enoic acid methyl ester(134765-49-4)
• EPA Substance Registry System: (6S,7R)-6-Hydroxy-7-trimethylsilanyl-non-8-enoic acid methyl ester(134765-49-4)

Safety Data

• Hazardous Substances Data: 134765-49-4(Hazardous Substances Data)

Upstream product

• 6654-36-0 methyl 6-oxohexanoate 
• 79309-68-5 4,4,5,5-Tetramethyl-2-<(2E)-3-(trimethylsilyl)-2-propenyl>-1,3,2-dioxaborolane 

Relevant articles and documents

LiBF4: A mild lewis acid for intramolecular diels-alder reactions

The lithium salts, LiClO4 and LiBF4, have been investigated for their potential use as Lewis acid catalysts in the intramolecular Diels-Alder reaction. No cycloaddition of the trienone, 1, is observed when LiClO4 is used. LiBF4 provides quantitative yield of the cis-fused cycloadduct in 72 hours at room temperature. The catalysis is ascribed to the slow release of BF3 rather than to the lithium cation.