1347748-75-7Relevant academic research and scientific papers
Controlled rearrangement of lactam-tethered allenols with brominating reagents: A combined experimental and theoretical study on α-versus β-keto lactam formation
Alcaide, Benito,Almendros, Pedro,Luna, Amparo,Cembellin, Sara,Arno, Manuel,Domingo, Luis R.
supporting information; experimental part, p. 11559 - 11566 (2011/11/29)
N-Bromosuccinimide (NBS) smoothly promotes the ring expansion of lactam-tethered allenols to efficiently afford cyclic α- or β-ketoamides with good yields and high chemo-, regio-, and diastereoselectivity, through controlled C-C bond cleavage of the β- or
