134784-75-1Relevant academic research and scientific papers
Atropisomerism in Doubly peri-Substituted 9-(2-methylbenzyl)triptycene Derivatives, 8-Chloro- and 8-Bromo-1,4-dimethyl-9-(2-methylbenzyl)triptycenes
Yamamoto, Gaku,Nemoto, Takashi,Ohashi, Yuji
, p. 1957 - 1966 (2007/10/02)
The 13C dynamic NMR study revealed that 9-(2-methylbenzyl)triptycene has an energy barrier to gear rotation of 11.8 kcal*mol-1 (1 cal=4.184 J).Introduction of substituents at two of the peri-positions was expected to raise the barrier enough fo
Isomerization of Atroisomeric Triptycene Derivatives in Solid States
Yamamoto, Gaku
, p. 741 - 744 (2007/10/02)
The sc* (9S*) rotamers of 8-bromo- and 8-chloro-1,4-dimethyl-9-(2-methylbenzyl)triptycenes irreversibly isomerize to the corresponding ap rotamers in solid states at the temperature range of 170 to 200 deg C.
