134834-30-3Relevant academic research and scientific papers
Enantioselective Addition of Diethylzinc to Aldehydes using Chiral Polymer Catalysts Possessing a Methylene Spacer
Watanabe, Masami,Soai, Kenso
, p. 837 - 842 (2007/10/02)
N-Butylnorephedrine supported on polystyrene resin via a six-methylene spacer catalyses the enantioselective addition of diethylzinc to both aromatic and aliphatic aldehydes, providing optically active secondary alcohols in good to high enantiomeric excesses.In the enantioselective addition of diethylzinc to an aliphatic aldehyde, polymer catalyst with a six-methylene spacer is more enantioselective than other previously reported polymer catalysts.
New Polymer Bound Chiral Catalyst with Methylene Spacer for the Enantioselective Addition of Diethylzinc to Aldehydes
Soai, Kenso,Watanabe, Masami
, p. 97 - 100 (2007/10/02)
Optically active sec-alcohols in good to high e.e.'s were obtained from the enantioselective addition of diethylzinc to both aliphatic and aromatic aldehydes using a polymer attached chiral catalyst with a methylene spacer.
