134834-33-6Relevant academic research and scientific papers
Novel recyclable aminoalcohol salts in catalytic asymmetric inductions. The addition of diethylzinc to aromatic aldehydes
Hailes, Helen C.,Madden, James
, p. 105 - 107 (2007/10/03)
Novel recyclable benzyloxyalkyl norephedrine salts have been used as efficient catalysts for the addition of diethylzinc to aromatic aldehydes to give the corresponding secondary alcohols in up to 82% ee.
Enantioselective Addition of Diethylzinc to Aldehydes using Chiral Polymer Catalysts Possessing a Methylene Spacer
Watanabe, Masami,Soai, Kenso
, p. 837 - 842 (2007/10/02)
N-Butylnorephedrine supported on polystyrene resin via a six-methylene spacer catalyses the enantioselective addition of diethylzinc to both aromatic and aliphatic aldehydes, providing optically active secondary alcohols in good to high enantiomeric excesses.In the enantioselective addition of diethylzinc to an aliphatic aldehyde, polymer catalyst with a six-methylene spacer is more enantioselective than other previously reported polymer catalysts.
New Polymer Bound Chiral Catalyst with Methylene Spacer for the Enantioselective Addition of Diethylzinc to Aldehydes
Soai, Kenso,Watanabe, Masami
, p. 97 - 100 (2007/10/02)
Optically active sec-alcohols in good to high e.e.'s were obtained from the enantioselective addition of diethylzinc to both aliphatic and aromatic aldehydes using a polymer attached chiral catalyst with a methylene spacer.
