134900-14-4

Basic information

• Product Name: ((1S,2S)-2,3,3-Trimethyl-1-vinyl-butylsulfanyl)-benzene
• CAS NO: 134900-14-4
• Molecular Weight: 234.406
• Mol File: 134900-14-4.mol

Chemical Properties

• CAS DataBase Reference: ((1S,2S)-2,3,3-Trimethyl-1-vinyl-butylsulfanyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((1S,2S)-2,3,3-Trimethyl-1-vinyl-butylsulfanyl)-benzene(134900-14-4)
• EPA Substance Registry System: ((1S,2S)-2,3,3-Trimethyl-1-vinyl-butylsulfanyl)-benzene(134900-14-4)

Safety Data

• Hazardous Substances Data: 134900-14-4(Hazardous Substances Data)

Upstream product

• 134933-66-7 4,5,5-trimethyl-hex-2t-ene 
• 134900-06-4 Trimethyl-((E)-4,5,5-trimethyl-hex-2-enyl)-silane 
• 931-59-9 benzenesulfenyl chloride 

Relevant articles and documents

ACYCLIC STEREOSELECTION IN THE REACTION OF CHIRAL ALLYLSILANES WITH ELECTROPHILES

The presence of a stereocenter close to the double bond of an allylsilane has an influence on the stereochemistry of the reaction with electrophiles.The stereoselectivity follows the rule of electrophilic attack on a trigonal carbon adjacent to a stereogenic center proposed by Houk.From chiral allylsilanes and achiral aldehydes it is possible to prepare homo allyl alcohols with three stereocenters with a good stereoselectivity.