134906-25-5Relevant academic research and scientific papers
Solvent Effects on Manganese(III)-Based Oxidative Free-Radical Cyclizations: Ethanol and Acetic Acid
Snider, Barry B.,Merritt, John E.,Dombroski, Mark A.,Buckman, Brad O.
, p. 5544 - 5553 (2007/10/02)
Ethanol complements the typical solvent, acetic acid, for Mn(III)-based oxidative free-radical cyclizations.Cyclization of enol ether 1c to give gibberellic acid intermediate 6c is successfull in ethanol, but not in acetic acid.Ethanol acts as a reducing
