1349171-28-3

Basic information

• Product Name: 2-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]pyridine
• Synonyms: 2-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]pyridine
• CAS NO: 1349171-28-3
• Molecular Formula: C₁₇H₂₀BNO₂
• Molecular Weight: 281.1572
• Mol File: 1349171-28-3.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]pyridine(1349171-28-3)
• EPA Substance Registry System: 2-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]pyridine(1349171-28-3)

Safety Data

• Hazardous Substances Data: 1349171-28-3(Hazardous Substances Data)

Usage

Molecular structure

The chemical 2-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]pyridine is a pyridine-based compound containing a boron-containing phenyl group.

Type of compound

It is a ligand used in organometallic and coordination chemistry.

Usage

It is particularly used in the synthesis of transition metal complexes.

Reactivity and coordination properties

The presence of the borane group in the molecule provides unique reactivity and coordination properties, making it valuable for catalytic and synthetic applications.

Stability and versatility

The tetramethyl substitution on the borane group enhances its stability and makes it a versatile building block in the development of new materials and pharmaceuticals.

Applications

The chemical has important applications in academic and industrial research in various fields of chemistry.

Upstream product

• 1008-89-5 2-phenylpyridine 
• 73183-34-3 bis(pinacol)diborane 
• 89346-48-5 2-(2-fluorophenyl)pyridine 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Downstream Products

• 33421-36-2 2-(pyridine-2-yl)phenol 

Relevant articles and documents

Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin

An ortho-selective C-F bond borylation between N-heterocycle-substituted polyfluoroarenes and Bpin-Bpin with simple and commercially available [Rh(cod)2]BF4 as a catalyst is now reported. The reaction proceeds under mild reaction con

Ruthenium(II) Biscarboxylate-Catalyzed Borylations of C(sp2)?H and C(sp3)?H Bonds

Versatile borylations of C(sp2)?H and C(sp3)?H were achieved with ruthenium(II) biscarboxylate complexes. The robust nature of the ruthenium(II) catalyst enabled C(sp3)?H borylation on pyrrolidines, piperidines, and azepan

N-heterocyclic carbene enabled rhodium-catalyzed ortho C(sp2)-H borylation at room temperature

We report a rhodium-catalyzed ortho C(sp2)-H borylation of 2-phenylpyridines using commercially available N-heterocyclic carbenes (NHCs) as ligand and pinacolatodiboron (B2pin2) as borylating reagent. The reaction could take place at room temperature, tolerating a wide range of functionalities and affording ortho borylated products in moderate to excellent yields. The current method is also applicable to gram-scale reaction with reduced catalyst loading.

Directed: Ortho C-H borylation catalyzed using Cp?Rh(iii)-NHC complexes

Cp?Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild conditions.