13494-92-3Relevant articles and documents
Kinetics and products of the IO self-reaction
Bloss, William J.,Rowley, David M.,Cox, R. Anthony,Jones, Roderic L.
, p. 7840 - 7854 (2007/10/03)
The absorption cross-sections of the gas-phase IO radical and the kinetics of the products of the IO self-reaction was measured using laser photolysis with time-resolved ultraviolet (UV)-vis absorption spectroscopy. The IO cross sections exhibited a negative temperature dependence. Results showed the formation of a broadband absorbing product underlying the IO absorption at low wavelengths.
Kinetics of the IO radical. 1. Reaction of IO with ClO
Turnipseed, Andrew A.,Gilles, Mary K.,Burkholder, James B.,Ravishankara
, p. 5517 - 5525 (2007/10/03)
The rate coefficient for the IO + ClO → products (5) reaction was measured by coupling discharge flow and pulsed laser-induced fluorescence techniques. Rate coefficients were measured from 200 to 362 K by monitoring the temporal profile of IO in an excess of ClO. The rate coefficient is described by the expression: k5(T) = (5.1 ± 1.7) × 10-12 exp[(280 ± 80)/T] cm3 molecules-1 s-1 where the quoted uncertainties include estimated systematic errors. Atomic iodine was identified as a major product of reaction 5. A branching ratio of Φ = 0.14 ± 0.04 at 298 K was obtained for the sum of channels which do not produce I atoms.
