13495-04-0

Usage

Uses

In antifungal compositions.

InChI:InChI=1/C7H16O4S.Na/c1-2-3-4-5-6-7(8)12(9,10)11;/h7-8H,2-6H2,1H3,(H,9,10,11);/q;+1/p-1

Upstream product

• 111-70-6 n-heptan1ol 
• 111-71-7 heptanal 

Downstream Products

• 7664-93-9 sulfuric acid 
• 95513-28-3 (2S)-cis-1-(phenylsulfonyl)-2-(1-<(phenylsulfonyl)oxy>butyl)-5-heptylpyrrolidine 
• 95513-21-6 (2S)-cis-1-benzyl-5-heptylproline tert-butyl ester 
• 95513-23-8 (2S)-trans-1-benzyl-5-heptylproline tert-butyl ester 
• 95513-29-4 (2S)-cis-5-butyl-2-heptyl-1-(phenylsulfonyl)pyrrolidine 
• 95513-54-5 1-((2S,5S)-1-Benzyl-5-heptyl-pyrrolidin-2-yl)-butan-1-one 
• 95513-24-9 (2S)-cis-1-benzyl-5-heptylproline 
• 95513-25-0 (2S)-cis-1-benzyl-2-(1-hydroxybutyl)-5-heptylpyrrolidine 
• 95587-06-7 (2R,5S)-1-Benzyl-5-heptyl-pyrrolidine-2-carbonitrile 
• 95513-33-0 (2S,5S)-1-Benzyl-5-heptyl-pyrrolidine-2-carbonitrile 
• 95513-16-9 (2S)-1-benzyl-5-(1-<(benzyloxy)carbonyl>heptylidene)proline tert-butyl ester 
• 95513-14-7 benzyl 2-(<(trifluoromethyl)sulfonyl>oxy)octanoate 
• 95513-39-6 (5S)-1-benzyl-2-butyl-5-heptylproline tert-butyl ester 
• 95513-27-2 (2S)-cis-1-(phenylsulfonyl)-2-(1-hydroxybutyl)-5-heptylpyrrolidine 

Relevant academic research and scientific papers

A TEMPO-like nitroxide combined with an alkyl-substituted pyridine: An efficient catalytic system for the selective oxidation of alcohols with iodine

An efficient method for the oxidation of alcohols to aldehydes or ketones in a two-phase CH2Cl2/NaHCO3 (aq.) system, using iodine and catalytic amounts of 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl and 2,4,6-trimethylpyridine, was developed. The performance of the method was demonstrated by the selective oxidation of 37 variously substituted alcohols in ≥90% yield, including the gram-scale synthesis of the important chemical 2,5-diformylfuran from biomass-derived 5-hydroxylmethylfurfural.

α-Amino Acids as Chiral Educts for Asymmetric Products. Chirospecific Syntheses of the 5-Butyl-2-heptylpyrrolidines from Glutamic Acid

Both enantiomers of trans-5-butyl-2-heptylpyrrolidine, an active and major component in the repellent venom of the ant Solenopsis fugax, have been synthesized with very high diastereomeric and optical purity from glutamic acid.Both enantiomers of the cis isomer also have been synthesized in an extension of our methodology to encompass the preparation of both cis and trans, optically pure, 2,5-disubstituted pyrrolidines and because of their potential entomological interest.Initially, a sulfide contraction process efficiently introduces the first side chain onto a pyroglutamate intermediate.Various strategies to elaborate the second side chain have been developed along with methods to control and establish the relative steroechemistry at C-2 and C-5 of the pyrrolidine ring with high selectivity. 2,5-Dialkyl-1-pyrrolidines, which also have been identified in the ant venom, can be prepared by these processes as well with specific absolute stereochemistry.

A NOVEL AND VERSATILE SEPARATION METHOD FOR ALDEHYDES

An aqueous solution of sodium ε-amino-n-caproate can be used for efficient and simple separation of aldehydes, overcoming the difficulties associated with the NaHSO3 method.Keywords - separation of aldehydes; Schiff base of amino acid; ω-amino acid; sodium ε-amino-n-caproate; sodium bisulfite adduct of aldehydes