1349842-76-7

Basic information

• Product Name: 6-bromo-4-hydroxy-3-methoxy-2,4-dimethylcyclohexa-2,5-dienone
• Synonyms: 6-bromo-4-hydroxy-3-methoxy-2,4-dimethylcyclohexa-2,5-dienone
• CAS NO: 1349842-76-7
• Molecular Weight: 247.089
• Mol File: 1349842-76-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-bromo-4-hydroxy-3-methoxy-2,4-dimethylcyclohexa-2,5-dienone(CAS DataBase Reference)
• NIST Chemistry Reference: 6-bromo-4-hydroxy-3-methoxy-2,4-dimethylcyclohexa-2,5-dienone(1349842-76-7)
• EPA Substance Registry System: 6-bromo-4-hydroxy-3-methoxy-2,4-dimethylcyclohexa-2,5-dienone(1349842-76-7)

Safety Data

• Hazardous Substances Data: 1349842-76-7(Hazardous Substances Data)

Upstream product

• 1008450-83-6 4-(benzyloxy)-2-methoxy-3-methylbenzaldehyde 
• 1008450-80-3 4-(benzyloxy)-2-hydroxy-3-methylbenzaldehyde 
• 6248-20-0 2,4-dihydroxy-3-methylbenzaldehyde 
• 608-25-3 2-methylbenzene-1,3-diol 
• 1349842-72-3 6-bromo-3-methoxy-2,4-dimethylphenol 
• 81633-95-6 3-methoxy-2,4-dimethylphenol 

Downstream Products

• 1349842-79-0 5-bromo-2-methoxy-1,3-dimethyl-4-oxocyclohexa-2,5-dien-1-yl-tert-butyl malonate 

Relevant articles and documents

Regioselective and stereoselective cyclizations of cyclohexadienones tethered to active methylene groups

The cyclization of 2,5-cyclohexadienones tethered to activated methylene groups was studied. The substitution around the cyclohexadienone ring serves to regioselectively direct these cyclizations based primarily on electronic effects. In the case of brominated substrates, these reactions proceed to give highly unusual electron-deficient tricyclic cyclopropanes. By using a Cinchona alkaloid-based phase-transfer catalyst, prochiral cyclohexadienones can be desymmetrized with moderate stereoselectivity.