1350371-63-9Relevant academic research and scientific papers
Compartmentalization of Incompatible Polymers within Metal–Organic Frameworks towards Homogenization of Heterogeneous Hybrid Catalysts for Tandem Reactions
Zhao, Jin-Hao,Yang, Yong,Che, Jin-Xin,Zuo, Jun,Li, Xiao-Hua,Hu, Yong-Zhou,Dong, Xiao-Wu,Gao, Liang,Liu, Xin-Yuan
supporting information, p. 9903 - 9909 (2018/07/25)
New catalytic systems that contain incompatible catalytic sites were constructed by the in situ polymerization of acidic and basic polymers into metal–organic frameworks, which resulted in highly porous, recyclable, and durable catalytic composites with excellent compartmentalization, so that opposing agents were spatially isolated. These synthesized hybrid catalysts exhibited excellent catalytic activity for one-pot “wolf and lamb” reactions (deacetalization/Knoevenagel or Henry), which was attributed to their unique characteristic of having a locally homogeneous, but globally heterogeneous, structure.
