1350553-45-5

Basic information

• Product Name: methyl 5-((5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl)ethynyl)picolinate
• Synonyms: methyl 5-((5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl)ethynyl)picolinate
• CAS NO: 1350553-45-5
• Molecular Weight: 441.428
• Mol File: 1350553-45-5.mol

Chemical Properties

• CAS DataBase Reference: methyl 5-((5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl)ethynyl)picolinate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-((5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl)ethynyl)picolinate(1350553-45-5)
• EPA Substance Registry System: methyl 5-((5-tert-butyl-2-(trifluoromethylsulfonyloxy)phenyl)ethynyl)picolinate(1350553-45-5)

Safety Data

• Hazardous Substances Data: 1350553-45-5(Hazardous Substances Data)

Upstream product

• 29682-15-3 methyl 5-bromopicolinate 
• 217966-72-8 4-(tert-butyl)-2-iodophenyltrifluoromethane sulfonate 
• 17880-61-4 methyl 5-ethynylpyridine-2-carboxylate 

Downstream Products

• 1350553-51-3 methyl 5-((5-tert-butyl-2-ethynylphenyl)ethynyl)picolinate 
• 1350553-54-6 dimethyl 5,5'-(6,6'-(buta-1,3-diyne-1,4-diyl)bis(3-tert-butyl-6,1-phenylene)bis(ethyne-2,1-diyl))dipicolinate 
• 1350553-57-9 5,5'-(6,6'-(buta-1,3-diyne-1,4-diyl)bis(3-tert-butyl-6,1-phenylene)bis(ethyne-2,1-diyl))dipicolinic acid 
• 1350553-48-8 methyl 5-((5-tert-butyl-2-((triisopropylsilyl)ethynyl)phenyl)ethynyl)picolinate 

Relevant articles and documents

Fluorogenic N,O-chelates built on a C2-symmetric aryleneethynylene platform: Spectroscopic and structural consequences of conformational preorganization and ligand denticity

Using π-extended aryleneethynylene as a rigid structural skeleton, a C2-symmetric bis(picolinate) ligand was prepared. Binding of zinc(II) or cadmium(II) ion to this formally tetradentate N2O 2-chelate resulted in significant red-shifts and enhancement in emission. The metal-ligand interaction responsible for such structural change was investigated by isolation and characterization of a tetrazinc(II) complex, in which the picolinate group functions not only as terminal bidentate but also as bridging with its μ-1,3 carboxylate unit.