135056-64-3

Upstream product

• 43209-86-5 3-trimethylsilyl-3-buten-2-one 
• 109001-55-0 methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-arabino-hexopyranoside-2-ulose 

Downstream Products

• 135056-65-4 Methyl 3,2-C<(3'S)-3'-Benzoyloxybutan-1'-yl-4'-ylidene>-4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-α-D-arabino-hexopyranoside 
• 127783-21-5 Methyl 4,6-O-Bezylidene-2,3-dideoxy-3,2-C-<(3'S)-3'-hydroxybutan-1'-yl-4'-ylidene>-3-C-methyl-α-D-arabino-hexopyranoside 
• 127910-93-4 Methyl 4,6-O-Benzylidene-2,3-dideoxy-3,2-C-<(3'R)-3'-hydroxybutan-1'-yl-4'-ylidene>-3-C-methyl-α-D-arabino-hexopyranoside 
• 109001-58-3 Methyl 4,6-O-Benzylidene-3-deoxy-3-C-methyl-3,2-C-(3'-oxobutan-1'-yl-4'-ylidene)-α-D-arabino-hexopyranoside 

Relevant academic research and scientific papers

Robinson Annulation on a Carbohydrate Derivative

The reactions of an enolate derived from methyl 4,6-O-benzylidene-3-deoxy-3-C-methyl-α-D-arabino-hexopyranosid-2-ulose have been studied; examples of O-alkylation, C-alkylation and Robinson annulation were observed.In the latter case the structure of the product was confirmed by X-ray crystallography on a crystalline allylic alcohol prepared by reduction of the ketone produced in the reaction.