1350660-96-6

Basic information

• Product Name: ethyl 3-(propa-1,2-dien-1-yl)benzoate
• Synonyms: ethyl 3-(propa-1,2-dien-1-yl)benzoate
• CAS NO: 1350660-96-6
• Molecular Weight: 188.226
• Mol File: 1350660-96-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 3-(propa-1,2-dien-1-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-(propa-1,2-dien-1-yl)benzoate(1350660-96-6)
• EPA Substance Registry System: ethyl 3-(propa-1,2-dien-1-yl)benzoate(1350660-96-6)

Safety Data

• Hazardous Substances Data: 1350660-96-6(Hazardous Substances Data)

Upstream product

• 146432-19-1 B-allenyl-9-BBN 
• 58313-23-8 3-iodobenzoic acid methyl ester 
• 50-00-0 formaldehyd 
• 178742-95-5 ethyl 3-(ethynyl)benzoate 

Relevant articles and documents

Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes

Copper-catalyzed silylation of aryl allenes using a silylborane reagent affords vinyl silane building blocks with high efficiency. The use of a seven-membered NHC ligand proved crucial for high regioselectivity. The catalytically generated allylcoppper intermediates were intercepted by aldehydes in a diastereoselective three-component coupling to furnish homoallylic alcohols. Seven′s up! The use of a seven-membered N-heterocyclic carbene (NHC) ligand proved crucial in exerting high regiocontrol during the development of the first copper-catalyzed silylation of allenes using a commercial silylborane reagent. The process affords privileged vinyl silane building blocks with high efficiency. Allylcopper intermediates can be intercepted by aldehydes in a highly diastereoselective three-component coupling to furnish homoallylic alcohols.