1350660-99-9Relevant academic research and scientific papers
Suzuki-miyaura cross coupling reactions of b-Allenyl-9-BBN
Radkowski, Karin,Seidel, Guenter,Fuerstner, Alois
experimental part, p. 950 - 952 (2011/12/05)
Despite the tremendously wide scope of the palladiumcatalyzed SuzukiMiyaura cross coupling, boron-based allenylation reactions of aryl halides are virtually unknown. It is now demonstrated that the borate complex formed in situ from B-allenyl-9-BBN and NaOMe in DMF allows aryl- and heteroaryl iodides to be allenylated under mild conditions.
