1350662-66-6Relevant articles and documents
Copper-catalyzed conjugate additions of alkylboranes to aryl α,β-Unsaturated Ketones
Ohmiya, Hirohisa,Shido, Yoshinori,Yoshida, Mika,Sawamura, Masaya
, p. 928 - 930 (2011/12/05)
Conjugate addition of alkylboron compounds (alkyl-9-BBN) to aryl α,β-unsaturated ketones proceeded in the presence of a catalytic amount (10 mol%) of [(IPr)CuCl] and t-BuOK. The alkylboranes are available through alkene hydroboration, and thus the overall process represents a reductive conjugate addition of alkenes to enone derivatives. A variety of functional groups are tolerated in both the alkenes and the α,β- unsaturated ketones.