1350707-14-0

Basic information

• Product Name: tert-butyl (1S,2R)-2-bromo-2-formyl-1-phenylcyclopropanecarboxylate
• Synonyms: tert-butyl (1S,2R)-2-bromo-2-formyl-1-phenylcyclopropanecarboxylate
• CAS NO: 1350707-14-0
• Molecular Weight: 325.202
• Mol File: 1350707-14-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-butyl (1S,2R)-2-bromo-2-formyl-1-phenylcyclopropanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl (1S,2R)-2-bromo-2-formyl-1-phenylcyclopropanecarboxylate(1350707-14-0)
• EPA Substance Registry System: tert-butyl (1S,2R)-2-bromo-2-formyl-1-phenylcyclopropanecarboxylate(1350707-14-0)

Safety Data

• Hazardous Substances Data: 1350707-14-0(Hazardous Substances Data)

Upstream product

• 14925-39-4 2-bromoacrolein 
• 72410-67-4 tert-butyl 2-diazo-2-phenylacetate 
• 16537-09-0 t-butyl phenylacetate 

Relevant articles and documents

Erratum: Oxazaborolidinium Ion-Catalyzed Cyclopropanation of α-Substituted Acroleins: Enantioselective Synthesis of Cyclopropanes Bearing Two Chiral Quaternary Centers (J. Am. Chem. Soc. (2011) 133:51 (20708?20711) DOI: 10.1021/ja209270e)

Pages 20709 and 20710. In the published version of the paper, the trans:cis ratios of 2w and 2x were reversed. The revised results were confirmed by NOE experiments and comparison of the optical rotation data with reported values after transformation. The