135075-18-2Relevant academic research and scientific papers
Basket-shaped Molecular Cavity-Containing Donor Centres - Synthesis, Structure, Properties
Breitenbach, Joerg,Rissanen, Kari,Wolf, Ute U.,Voegtle, Fritz
, p. 2323 - 2327 (2007/10/02)
The macrocyclic basket-shaped molecule 2, composed of three 4-donor-substituted pyridine units, is synthesized by cyclisation of the chloromethyl compound 7 with sulfonamide 8.The X-ray structure analysis of 2 gives an impression of the shape of the molecular basket.Furthermore it demonstrates that the toluenesulfonamide residues interlink, creating dimeric units of 2 in the crystal.Key Words: Basket-shaped molecules / Pyridine derivatives / Macrocyclic compounds / Heterocyclic compounds / Supramlecular chemistry
