1350810-15-9Relevant academic research and scientific papers
Palladium-catalyzed cyclization of vinyl iodide-tethered allensulfonamide
Xie, Zheng,Wu, Pan,Cai, Liangzhen,Tong, Xiaofeng
, p. 2160 - 2162 (2014/04/03)
This Letter describes a palladium-catalyzed cyclization of vinyl iodide-tethered allensulfonamide in the presence of alkylol, which provides a facile access to 2-alkoxy-3-methylene-tetrahydropyridine. The asymmetric version of this reaction has also been preliminarily realized with up to 81% enantioselectivity when chiral bisphosphine ligands were used.
Synthesis of 3-pyrroline via domino Heck-aza-Michael reaction
Wu, Pan,Liu, Hui,Tong, Xiaofeng
, p. 4673 - 4675 (2012/09/05)
This Letter describes the Pd(0)-catalyzed domino Heck-aza-Michael reaction between (Z)-N-(3-iodoallyl)-tosylamide and acrylic ester. The reaction provides a facile access to an important class of substituted 3-pyrroline.
Palladium-catalyzed Heck-type reaction of oxime ether bearing a pendant vinyl iodide moiety
Liu, Hui,Wang, Limin,Tong, Xiaofeng
, p. 12206 - 12208 (2011/12/16)
A Pd(0)-catalyzed intramolecular Heck-type reaction of oxime ether has been developed, providing convenient access to heterocyclic oximes. The Royal Society of Chemistry 2011.
