1350844-06-2Relevant academic research and scientific papers
Rhodium-catalyzed highly stereoselective hydroselenation of internal alkynes bearing an electron-withdrawing group
Kawaguchi, Shin-Ichi,Kotani, Mao,Atobe, Shingo,Nomoto, Akihiro,Sonoda, Motohiro,Ogawa, Akiya
, p. 6766 - 6769 (2012/02/05)
Rhodium-catalyzed highly regio- and stereoselective hydroselenation of internal alkynes bearing an electron-withdrawing group took place to give (E)-vinyl selenides in good yields. The excellent syn stereoselectivity of this rhodium-catalyzed hydroselenation is of great importance in terms of complementing the previously reported hydroselenation of alkynes.
