135086-01-0Relevant academic research and scientific papers
DIVERGENTLY STEREOCONTROLLED REACTION OF AN ALLYLIC SILANE BEARING AN ASYMMETRIC ETHEREAL CARBON TOWARD ALDEHYDES
Nishigaichi, Yutaka,Takuwa, Akio,Jodai, Akifumi
, p. 2383 - 2386 (2007/10/02)
Lewis acid mediated allylation of aldehydes by an allylsilane bearing an asymmetric ethereal functionality proceeded in divergently stereocontrolled manners, i. e., TiCl4 afforded the syn isomer, whereas BF3*OEt2 afforded the anti isomer predominantly.
