1350923-68-0

Basic information

• Product Name: 2-[(3,4,5-trimethoxyphenyl)ethynyl]cyclohept-1-enecarbaldehyde
• Synonyms: 2-[(3,4,5-trimethoxyphenyl)ethynyl]cyclohept-1-enecarbaldehyde
• CAS NO: 1350923-68-0
• Molecular Weight: 314.381
• Mol File: 1350923-68-0.mol

Chemical Properties

• CAS DataBase Reference: 2-[(3,4,5-trimethoxyphenyl)ethynyl]cyclohept-1-enecarbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(3,4,5-trimethoxyphenyl)ethynyl]cyclohept-1-enecarbaldehyde(1350923-68-0)
• EPA Substance Registry System: 2-[(3,4,5-trimethoxyphenyl)ethynyl]cyclohept-1-enecarbaldehyde(1350923-68-0)

Safety Data

• Hazardous Substances Data: 1350923-68-0(Hazardous Substances Data)

Upstream product

• 53560-33-1 3,4,5-trimethoxyphenylacetylene 
• 85236-13-1 2-bromocyclohept-1-ene-1-carbaldehyde 

Downstream Products

• 1350923-80-6 [2-((3,4,5-trimethoxyphenyl)ethynyl)cyclohept-1-enyl]methyl acetate 

Relevant articles and documents

Vinylogous nicholas reactions in the synthesis of icetexane, faveline, and related ring systems

The intramolecular vinylogous Nicholas reactions of aryl substituted acetoxy enyne-CoCO)complexes afford tricyclic 6,7,6-ring systems and related systems in good yield. Georg Thieme Verlag Stuttgart - New York.

Vinylogous Nicholas reactions in the synthesis of bi- and tricyclic cycloheptynedicobalt complexes

The Lewis acid mediated intramolecular Nicholas reactions of allylic acetate enyne-Co2(CO)6 complexes afford cycloheptenyne-Co2(CO)6 complexes in three manifestations. Electron rich aryl substituted alkyne complexes give tricyclic 6,7,x-benzocycloheptenyne complexes, with x = 5, 6, or 7. Allylsilane substituted complexes afford exo methylene bicyclic x,7-cycloheptenyne complexes (x = 6,7). The allyl acetate function may also be replaced by a benzylic acetate, to afford dibenzocycloheptyne-Co2(CO)6 complexes. Following reductive complexation, the methodology may be applied to the synthesis of the icetexane diterpene carbon framework.