1350923-70-4

Basic information

• Product Name: C₂₅H₂₆FNO₂
• Synonyms: C₂₅H₂₆FNO₂
• CAS NO: 1350923-70-4
• Molecular Weight: 391.485
• Mol File: 1350923-70-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₅H₂₆FNO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₅H₂₆FNO₂(1350923-70-4)
• EPA Substance Registry System: C₂₅H₂₆FNO₂(1350923-70-4)

Safety Data

• Hazardous Substances Data: 1350923-70-4(Hazardous Substances Data)

Upstream product

• 7517-19-3 methyl (L)-leucinate hydrochloride 
• 78603-97-1 (S)-2-amino-1,1-diphenyl-4-methylpentan-1-ol 
• 393-52-2 2-Fluorobenzoyl chloride 
• 61-90-5 L-leucine 

Downstream Products

• 1350923-72-6 (S)-2-(2-fluorophenyl)-4-isobutyl-5,5-diphenyl-4,5-dihydrooxazole 
• 1350923-67-9 C₃₇H₃₄NOP 

Relevant articles and documents

Design, synthesis, and applications of potential substitutes of t-Bu-phosphinooxazoline in Pd-catalyzed asymmetric transformations and their use for the improvement of the enantioselectivity in the Pd-catalyzed allylation reaction of fluorinated allyl enol carbonates

The design, synthesis, and applications of potential substitutes of t-Bu-PHOX in asymmetric catalysis is reported. The design relies on the incorporation of geminal substituents at C5 in combination with a substituent at C4 other than t-butyl (i-Pr, i-Bu, or s-Bu). Most of these new members of the PHOX ligand family behave similarly in terms of stereoinduction to t-Bu-PHOX in three palladium-catalyzed asymmetric transformations. Electronically modified ligands were also prepared and used to improve the enantioselectivity in the Pd-catalyzed allylation reaction of fluorinated allyl enol carbonates.