1350934-06-3Relevant academic research and scientific papers
HSAB-driven regioselectivity difference in the Lewis-acid catalyzed reactions of 2-C-substituted glycals with sulfur and oxygen nucleophiles: Direct versus allylic substitution
Nagaraj, Paramathevar,Ramesh, Namakkal G.
experimental part, p. 9322 - 9328 (2011/12/03)
A remarkable regioselectivity difference in the Lewis-acid catalyzed reactions of 2-C-acteoxymethyl glycals with thiophenols and phenols has been observed. The reaction with thiophenols led to preferential formation of a new class of compounds viz. 2-C-ar
