135103-64-9Relevant academic research and scientific papers
A novel nucleophilic substitution of in situ generated 3-tert-butyldimethyl-silyloxyalk-2-enylsulfonium salts with allylindium reagents
Lee, Phil Ho,Lee, Kooyeon,Kim, Sunggak
, p. 3205 - 3207 (2001)
(equation presented) In situ generated 3-tert-butyldimethylsilyloxyalk-2-enylsulfonium salts derived from the reaction of α,β-enones with dimethyl sulfide in the presence of TBSOTf undergo a novel nucleophilic substitution with in situ generated allylindium reagents from indium and allyl halides to give silyl enol ethers of δ,ε-unsaturated ketones, which correspond to Michael addition products, in good yields. ? Korea Advanced Institute of Science and Technology.
Indium-mediated β-allylation, β-propargylation, and β-allenylation onto α,β-unsaturated ketones: Reactions of in-situ-generated 3-tert-butyldimethylsilyloxyalk-2-enylsulfonium salts with in-situ-generated organoindium reagents
Lee, Kooyeon,Kim, Hyunseok,Miura, Tomoya,Kiyota, Koichi,Kusama, Hiroyuki,Kim, Sunggak,Iwasawa, Nobuharu,Lee, Phil Ho
, p. 9682 - 9688 (2007/10/03)
3-tert-Butyldimethylsilyloxyalk-2-enylsulfonium salts, generated in situ from the reaction of α,β-enones with dimethyl sulfide in the presence of TBSOTf, underwent a novel nucleophilic substitution with allylindiums to give silyl enol ethers of δ,ε-alkeny
Trialkylsilyl triflate promoted conjugate addition of allylstannes to α,β-enones
Kim,Lee
, p. 25 - 29 (2007/10/02)
Trialkylsilyl triflates promote conjugate additon of allylstannes to α,β-enones to afford β-alkylated silyl enol ethers in high yields.
