135107-04-9Relevant academic research and scientific papers
Borinic Acid Catalyzed, Regioselective Chloroacylations and Chlorosulfonylations of 2,3-Epoxy Alcohols
Tanveer, Kashif,Jarrah, Kareem,Taylor, Mark S.
supporting information, p. 3482 - 3485 (2015/07/28)
In the presence of a borinic acid derived catalyst, 2,3-epoxy alcohols undergo couplings with acyl and sulfonyl chlorides. This transformation directly generates O-acylated or O-sulfonylated chlorohydrin diols, with significant levels of regioselectivity for both the ring-opening and O-functionalization steps.
Simple primary anilines as iminium catalysts for the epoxidation of α-substituted acroleins
Erkkilae, Anniina,Pihko, Petri M.,Clarke, Melanie-Rose
, p. 802 - 806 (2008/03/18)
Simple ortho-alkylated anilines have been shown to be excellent iminium catalysts for the epoxidation reaction of α-substituted acroleins. A range of different α-substituted acroleins give the epoxide products in good to excellent yields and good chemoselectivity.
