135129-41-8

Basic information

• Product Name: (S)-3-[(3R,4R,5R)-4,5-((R)-Benzylidenedioxy)-2-oxotetrahydropyran-3-yloxycarbonylmethyl]-4-[5-benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-...
• Synonyms: (S)-3-[(3R,4R,5R)-4,5-((R)-Benzylidenedioxy)-2-oxotetrahydropyran-3-yloxycarbonylmethyl]-4-[5-benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-...
• CAS NO: 135129-41-8
• Molecular Weight: 1362.82
• Mol File: 135129-41-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-[(3R,4R,5R)-4,5-((R)-Benzylidenedioxy)-2-oxotetrahydropyran-3-yloxycarbonylmethyl]-4-[5-benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-...(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-[(3R,4R,5R)-4,5-((R)-Benzylidenedioxy)-2-oxotetrahydropyran-3-yloxycarbonylmethyl]-4-[5-benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-...(135129-41-8)
• EPA Substance Registry System: (S)-3-[(3R,4R,5R)-4,5-((R)-Benzylidenedioxy)-2-oxotetrahydropyran-3-yloxycarbonylmethyl]-4-[5-benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-...(135129-41-8)

Safety Data

• Hazardous Substances Data: 135129-41-8(Hazardous Substances Data)

Upstream product

• 135100-97-9 4-[5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-tribromoethoxycarbonyl)-3-(2-trimethylsilylethoxycarbonylmethyl)-4,5-dihydrodipyrrin-1(10H)-one 
• 135100-96-8 4-[5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethylpyrrol-2-ylmethyl]-7-carboxymethyl-2,8-bis(2-methoxycarbonylethyl)-9-(2,2,2-tribromoethoxycarbonyl)-3-(2-trimethylsilylethoxycarbonylmethyl)-4,5-dihydrodipyrrin-1(10H)-one 
• 183005-19-8 Dimethyl 1-(tert-butoxycarbonyl)-7-methoxycarbonylmethyl-9-(2,2,2-tribromoethoxycarbonyl)-3-(2-trimethylsilylethoxycarbonylmethyl)-5,10-dihydrodipyrrin-2,8-dipropionate 
• 183005-20-1 2,8-Bis(2-methoxycarbonylethyl)-7-methoxycarbonylmethyl-9-(2,2,2-tribromoethoxycarbonyl)-3-(2-trimethylsilylethoxycarbonylmethyl)-5,10-dihydrodipyrrin-1-carboxylic acid 
• 183005-21-2 5-[5-Iodo-4-(2-methoxycarbonyl-ethyl)-3-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrol-2-ylmethyl]-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid 2,2,2-tribromo-ethyl ester 
• 183005-15-4 5-Acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-16-5 5-Acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrole-2-carboxylic acid 
• 183005-14-3 4-Carboxymethyl-3-(2-methoxycarbonyl-ethyl)-5-methyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-18-7 3-(2-Methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid 2,2,2-tribromo-ethyl ester 
• 183005-13-2 4-Iodo-3-(2-methoxycarbonyl-ethyl)-5-methyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 74839-04-6 2-[(E)-Hydroxyimino]-3-oxo-hexanedioic acid 1-benzyl ester 6-methyl ester 
• 20603-45-6 3,4-O-Benzylidene-D-(+)-ribonic acid δ-lactone 
• 183005-06-3 3-(2-Methoxycarbonyl-ethyl)-5-methyl-4-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrole-2-carboxylic acid benzyl ester 
• 183005-17-6 5-Acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-(2-trimethylsilanyl-ethoxycarbonylmethyl)-1H-pyrrole-2-carboxylic acid tert-butyl ester 

Downstream Products

• 135100-99-1 (S)-4-<5-Benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-2,8-bis(2-methoxycarbonylethyl)-3,7-bis(methoxycarbonylmethyl)-9-(2,2,2-tribromoethoxycarbonyl)-4,5-dihydrodipyrrin-1(10H)-one 

Relevant articles and documents

Biosynthesis of porphyrins and related macrocycles. Part 44. Synthetic and stereochemical studies on the proposed spiro intermediate for biosynthesis of the natural porphyrins

A route is devised for synthesis of both enantiomers of the spiro lactam 4. The enzyme uroporphyrinogen III synthase (cosynthetase), which converts hydroxymethylbilane 1 into uroporphyrinogen III 3, is competitively inhibited more than twenty times more s