1351395-75-9Relevant academic research and scientific papers
Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases
Beyler, Maryline,Ezzaher, Salah,Karnahl, Michael,Santoni, Marie-Pierre,Lomoth, Reiner,Ott, Sascha
, p. 11662 - 11664 (2011)
Mononuclear pentacoordinate iron complexes with a free coordination site were prepared as mimics of the distal Fe (Fed) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.
